hi kilt, sorry it took so long for me to get back to you. in reef keeping the variables that can skew one or many things is always present. when a person says he/she has a problem with one aspect of parameters and all others are ok then this leads to the belief that the test kit is in error. if this is true, can you take a sample elsewhere to be tested ie: fish store, friend? to elaborate a bit on the cations. calcium and alk pretty much run hand in hand with each other. high alk can be due to low calcium, and the reverse is true also)
to maintain alk calcium should be in the 380 to 400 ppm range (sea water is 425 - 450 ppm. the other major component of skewing alk is co2 if the water surface is obstructed then co2 can not escape leading to high alk. an air stone in the tank will drive off co2. as stated the deciding or limiting factors can only be eleminated one by one till the problem is solved. can you test your ca & get a different test of your alk? if you have live rock and aragonite substrate then there are really only 2 causes for high alk.