Bullitt,
How many filters are on your RODI?
A typical 6-stage system should be as follows for 0ppm :
SEDIMENT FILTER
ACTIVE CARBON FILTER
CARBON BLOCK FILTER
RO FILTER
DI FILTER
DI FILTER (optional for 7 stages)
ACTIVE CARBON FILTER
Maybe your RO filter is installed in reverse.
Sounds stupid, but it happens.
Maybe your pressure is too high.
Over pressure will force waste water through the RO.
Maybe it's time to replace the DI resin (or add a 2nd DI filter as a 7th stage).
Good luck.